In the global energy and industrial system, both coal and petroleum coke are important carbon-based raw materials. Coal has a long history and is an important raw material for energy supply. Petroleum coke is a by-product in the petroleum refining process, and its application has gradually expanded with the development in recent years. The two have similarities and differences in many aspects, and analyzing their differences is of great significance.
Daftar Isi
BeralihBasic Characteristics
Definition and Formation
Petroleum coke is the product obtained by thermal cracking of heavy oil after the distillation of crude oil to separate light and heavy oil. After the reaction is completed, petroleum coke eventually forms black blocks or granules, accompanied by the generation of by-products such as gas and light oil. According to the different properties of the raw oil and processing techniques, petroleum coke can be classified into types. And its quality is closely related to the sulfur content and heavy metal content of the petroleum raw materials.
Coal is a solid combustible mineral formed by complex biochemical and physicochemical changes in ancient plants. Influenced by factors such as sedimentary environment, pressure and temperature, it gradually transforms into different types of coal such as lignite, bituminous coal and anthracite.
Sifat Fisik
Appearance and Morphology
The appearance of petroleum coke is a black or dark gray honeycomb-like solid with metallic luster, which is usually in block or granular form. Coal has a variety of appearance colors, ranging from the brown of lignite to the black of anthracite. Its forms include block and powder, and bituminous coal often has distinct strip-like textures.
Density and Hardness
The density of petroleum coke is generally 1.3-1.9g/cm³, which has relatively high hardness and a hard texture. Due to different types, the density of coal varies greatly. For example, the density of lignite is approximately 0.9-1.2g/cm³, while that of anthracite can reach 1.4-1.9g/cm³. And its overall hardness is lower than that of petroleum coke, especially lignite which is relatively soft in texture.
Sifat Kimia
Elemental Composition
Petroleum coke is mainly composed of carbon, with a content of 80% to 97%, which also contains small amounts of hydrogen, sulfur, nitrogen, oxygen and other elements. The sulfur content of high-sulfur petroleum coke can even reach over 5%. Although the elemental composition of coal is also mainly carbon, there are significant differences among different types of coal. Lignite has a carbon content of about 60% to 77%, while anthracite has a carbon content exceeding 90%, which also contains a certain amount of minerals.
Calorific Value and ash content
The calorific value of petroleum coke is relatively high, which rang generally from 28 to 35MJ/kg. And it has a relatively low ash content, usually less than 1%. The calorific value of coal fluctuates greatly, for example, the calorific value of lignite is approximately 10-20 MJ/kg, and that of anthracite can reach 25-35 MJ/kg. And its ash content is relatively high, generally ranging from 10% to 30%, and for some inferior coal is even higher.
Application Fields
Pet Coke
Bidang Energi
Industrial Heating
In terms of industrial heating, you can use petroleum coke as fuel for industrial boilers. It can provide thermal energy for industries such as steel and cement.
Fuel for Power Generation
In some regions, it is mixed and burned with coal for power generation to enhance the efficiency of power generation.
Industri Metalurgi
Electrode Production
In the production of electrodes, high-quality petroleum coke is a key raw material for manufacturing high-power and ultra-high-power graphite electrodes. With the excellent electrical conductivity and high-temperature resistance, it can meet the requirements for electrode usage.
Carbon Additive
You can use it in the steelmaking and casting processes to effectively increase the carbon content of steel and cast iron.
Industri Kimia
Raw Material Production
As a raw material for production, it is used to produce chemical products such as calcium carbide and silicon carbide.
Carbon Material Preparation
In the preparation of bahan karbon, You can further process it to manufacture advanced carbon materials such as high-performance carbon fibers and carbon nanotubes.
Other Applications
Activated Carbon Manufacturing
Its well-developed pore structure endows karbon aktif with excellent adsorption performance, so you can use it to manufacture activated carbon.
Fuel Additives
Using it as a fuel additive can improve the combustion performance of the fuel.
Coal
Bidang Energi
Thermal Power Generation
Coal plays an important role in thermal power generation and most of the world’s electricity is generated by coal-fired units.
Central Heating
It provides an important heat source for winter heating in northern regions, which is especially widely applied in small and medium-sized cities and rural areas.
Industri Metalurgi
Coke Production
As the core application of coal in the metallurgical industry, coking coal is processed into coke through high-temperature dry distillation and used in blast furnace ironmaking.
High-Furnace Injection
In this process, by injecting finely ground coal powder into the blast furnace to replace part of the coke, the production cost can be reduced.
Industri Kimia
Coal Chemicals
The coal chemical industry, including coal-to-methanol and coal-to-olefins, etc., is an important way for the clean and efficient utilization of coal.
Coal Tar Processing
Coal tar processing can produce a variety of chemical raw materials, such as benzene, toluene, phenols, etc.
Other Applications
Building Materials Production
You can use coal to burn cement, lime, etc. Its ash and slag can be used as raw materials or filling materials to help improve the performance and output of building materials.
New Carbon Materials
Through technological innovation, it can also be used to prepare new types of carbon materials, such as graphene.
Environmental Impact
Carbon Emissions
The combustion of kokas minyak bumi and coal both produce a large amount of carbon dioxide, which are important carbon emission sources causing global warming. But due to the high carbon content of petroleum coke, the amount of carbon dioxide produced per unit mass of combustion is even higher.
Pollutants
The combustion of petroleum coke generates pollutants such as sulfur dioxide, nitrogen oxides and particulate matter. In addition to generating the above-mentioned pollutants, coal combustion also releases a large amount of heavy metal pollutants. So it will cause pollution to the atmosphere, soil and water.
Market and Economic Analysis
Market Supply and Demand
The supply and demand of the coal market are influenced by factors such as the global economic situation and energy policies. Although the growth rate of coal demand has slowed down, there is still considerable demand in developing countries. The supply and demand of the petroleum coke market are closely related to the scale of petroleum refining. Because of the expansion of the petrochemical industry, the output of petroleum coke has been continuously increasing. And the market competition of it has also become increasingly fierce.
Price Fluctuations
The price of coal is influenced by factors such as origin, quality, transportation costs and policy regulation, and fluctuates greatly. While the price of petroleum coke is closely related to the price of petroleum and the relationship between supply and demand. If the price of petroleum drops, the price of petroleum coke often decreases accordingly.
Kesimpulan
Petroleum coke and coal have similarities and differences in many aspects and are both important raw materials for energy and industry. Under the background of “dual carbon”, it is necessary to promote transformation and upgrading respectively. And providing better support for the development of energy and industry through innovation.